![]() A room-temperature sodium–sulfur battery with high capacity and stable cycling performance. The reduction of sulfuryl chloride at teflon-bonded carbon cathodes. A mathematical model of a lithium/thionyl chloride primary cell. Ultrahigh performance all solid-state lithium sulfur batteries: salt anion’s chemistry-induced anomalous synergistic effect. Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes. Properties and structure of the LiCl-films on lithium anodes in liquid cathodes. Lithium anode film and organic and inorganic electrolyte batteries. Investigations of the Safety of Li/SOCl 2 Batteries (1979).ĭey, A. Symposium on Battery Design and Optimization (Battery Division, Electrochemical Society, 1979).Ībraham, K. Activated microporous carbon nanospheres for use in supercapacitors. Extension of the Stöber method to the preparation of monodisperse resorcinol–formaldehyde resin polymer and carbon spheres. High power–high energy sodium battery based on threefold interpenetrating network. A 3.8-V earth-abundant sodium battery electrode. Ionic liquid analogs of AlCl 3 with urea derivatives as electrolytes for aluminum batteries. Nanostructured Li 2S–C composites as cathode material for high-energy lithium/sulfur batteries. Polysulfide-containing glyme-based electrolytes for lithium sulfur battery. Rechargeable lithium battery using non-flammable electrolyte based on tetraethylene glycol dimethyl ether and olivine cathodes. An operando X-ray diffraction study of chloroaluminate anion-graphite intercalation in aluminum batteries. High Coulombic efficiency aluminum-ion battery using an AlCl 3-urea ionic liquid analog electrolyte. An ultrafast rechargeable aluminium-ion battery. Rechargeable aluminum batteries: effects of cations in ionic liquid electrolytes. High-safety and high-energy-density lithium metal batteries in a novel ionic-liquid electrolyte. A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte. Studies in lithium oxyhalide cells for downhole instrumentation use of lithium tetrachlorogallate electrolyte in Li/SOCl 2 cells. Modeling self-discharge of Li/SOCl 2 cells. High rate discharge characteristics of Li/SOCl 2 cells. The effects of pore size on electrical performance in lithium-thionyl chloride batteries. Lithium inorganic batteries at high discharge rates. Mechanistic studies related to the safety of Li/SOCl 2 cells. Raman spectroscopic studies of the structure of electrolytes used in the Li/SOCl 2 battery. Investigation of SOCl 2 reduction by cyclic voltammetry and ac impedance measurements. ![]() The lithium-thionyl chloride battery-a review. The mechanisms of thionyl chloride reduction at solid electrodes. Mathematical modeling of the lithium, thionyl chloride static cell: II. Properties of LiAlCl 4–SOCl 2 solutions for Li/SOCl 2 battery. The reversible Cl 2/NaCl or Cl 2/LiCl redox in the microporous carbon affords rechargeability at the positive electrode side and the thin alkali-fluoride-doped alkali-chloride solid electrolyte interface stabilizes the negative electrode, both are critical to secondary alkali-metal/Cl 2 batteries. Here we show that with a highly microporous carbon positive electrode, a starting electrolyte composed of aluminium chloride in SOCl 2 with fluoride-based additives, and either sodium or lithium as the negative electrode, we can produce a rechargeable Na/Cl 2 or Li/Cl 2 battery operating via redox between mainly Cl 2/Cl − in the micropores of carbon and Na/Na + or Li/Li + redox on the sodium or lithium metal. This battery discharges by lithium oxidation and catholyte reduction to sulfur, sulfur dioxide and lithium chloride, is well known for its high energy density and is widely used in real-world applications however, it has not been made rechargeable since its invention 8, 9, 10, 11, 12, 13. Before the invention of secondary LIBs, the primary lithium-thionyl chloride (Li-SOCl 2) battery was developed in the 1970s using SOCl 2 as the catholyte, lithium metal as the anode and amorphous carbon as the cathode 1, 2, 3, 4, 5, 6, 7. Lithium-ion batteries (LIBs) are widely used in applications ranging from electric vehicles to wearable devices.
0 Comments
Leave a Reply. |
Details
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |